欧盟在2007年5月颁布了被认为是欧盟20年来最重要的一部法规:REACH法规,即1907/2006/EC《关于化学品注册、评估、授权和限制的法规》(简称REACH法规)。这是欧盟最新的一部化学法规,它于2007年6月1日正式生效,并从2008年6月1日起在欧盟正式实施。
REACH取代了欧盟现行的40项法规,成为一套统一的化学品注册、评估、许可和限制的管理法规。
2、欧盟REACH检测重点关注物质(138项):
第一批15种SVHC (2008年10月28日公布)
The first fifteen Substances of Very High Concern (Released in Oct, 2008)
1 Bis(tributyltin)oxide (TBTO) 三丁基氧化锡(TBTO)
2 Diarsenic pentaoxide* 五氧化二砷*
3 Diarsenic trioxide* 三氧化二砷*
4 Triethyl arsenate 三乙基砷酸酯
5 Lead hydrogen arsenate* 酸式砷酸铅*
6 Cobalt dichloride* 二氯化钴*
7 Sodium dichromate * 重铬酸钠二水合物*
8 Anthracene 蒽
9 4,4'-Diaminodiphenylmethane (MDA)4,4'-二氨基二苯基甲烷(MDA)
10 Dibutyl phthalate (DBP) 邻苯二甲酸二丁酯 (DBP)
11 Benzyl butyl phthalate (BBP) 邻苯二甲酸丁苄酯(BBP)
12 5-tert-butyl-2,4,6-trinitro-m-xylene (musk xylene)二甲苯麝香
13 Bis (2-ethylhexyl)phthalate (DEHP)邻苯二甲酸二(2-乙基己基)酯(DEHP)
14 Hexabromocyclododecane(HBCDD) andall major diastereoisomers identified
六溴环十二烷及其主要同分异构体(HBCDD)
15 Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) 短链氯化石蜡(SCCP)
第二批15 种SVHC (2010 年1 月13日公布,2010年3 月30日修订)
The second fifteen Substances of Very High Concern (Released in Jan, 2010 and Mar, 2010)
备注:2012-6-18 第二批的硅酸铝耐火陶瓷纤维、锆硅酸铝耐火陶瓷纤维已与第六批的硅铝耐火陶瓷纤维(RCF) 、
氧化锆硅酸铝耐火陶瓷纤维 (Zr-RCF)合并。
Note: 2012-6-18 The aluminosilicate refractory ceramic fibres (Al-RCF) and zirconia aluminosilicate refractory ceramic
fibres (ZrAl-RCF) included in the List in the second thirteen SVHC and The sixth twenty SVHC haved been consolidated.
16 16 Anthracene oil 蒽油
17 Anthracene oil, anthracene paste,distn. lights蒽油、蒽糊、轻油
18 Anthracene oil, anthracene paste,anthracene fraction蒽油、蒽糊、蒽馏分
19 Anthracene oil, anthracene-low 蒽油、少蒽
20 Anthracene oil, anthracene paste 蒽油、蒽糊
21 Pitch, coal tar, high temp. 高温煤沥青
Aluminosilicate Refractory Ceramic Fibres硅酸铝耐火陶瓷纤维
Zirconia Aluminosilicate Refractory Ceramic Fibres锆硅酸铝耐火陶瓷纤维
22 Acrylamide 丙烯酰胺
23 2,4-Dinitrotoluene 2,4-二硝基甲苯
24 Diisobutyl phthalate(DIBP) 邻苯二甲酸二异丁酯(DIBP)
25 Lead chromate* 铬酸铅*
26 Lead chromate molybdate sulphate red (C.I. Pigment Red 104)* 钼铬酸铅红(C.I.颜料红104)*
27 Lead sulfochromate yellow (C.I.Pigment Yellow 34)*铬酸铅黄(C.I.颜料黄34)*
28 Tris(2-chloroethyl)phosphate三(2-氯乙基)磷酸盐
第三批8 种SVHC (2010 年6 月18日公布)
The third eight Substances of Very High Concern (Released in Jun, 2010)TS
29 Trichloroethylene三氯乙烯
30 Boric acid* 硼酸*
31 Disodium tetraborate, anhydrous* 四硼酸钠,无水*
32 Tetraboron disodium heptaoxide, hydrate* 七水合硼酸钠* 1
33 Sodium chromate* 铬酸钠*
34 Potassium chromate* 铬酸钾*
35 Ammonium dichromate* 重铬酸铵*
36 Potassium dichromate* 重铬酸钾*
第四批8 种SVHC (2010 年12 月15日公布)
The fourth eight Substances of Very High Concern (Released in Dec, 2010)
37 Cobalt(II) sulphate* 硫酸钴*
38 Cobalt(II) dinitrate* 硝酸钴*
39 Cobalt(II) carbonate* 碳酸钴*
40 Cobalt(II) diacetate* 醋酸钴*
41 2-Methoxyethanol 乙二醇单甲醚
42 2-Ethoxyethanol 乙二醇单乙醚
43 Chromium trioxide* 三氧化铬*
44 Acids generated from chromium trioxide and their oligomers铬酸及其低聚物产生的酸类: Chromic acid* 铬酸*
Dichromic acid* 重铬酸*
Oligomers of chromic acid
and dichromic acid* 铬酸和重铬酸的低聚物*
第五批7 种SVHC (2011 年6月20日公布)
The fifth seven Substances of Very High Concern (Released in Jun, 2011)
45 2-Ethoxyethyl acetate 乙二醇乙醚乙酸酯
46 Strontium chromate* 铬酸锶*
47 1,2-Benzenedicarboxylic acid,di-C7-11-branched and linear alkyl esters(DHNUP)*
邻苯二甲酸二(C7-11支链与直链)烷基酯(DHNUP)*
48 Hydrazine 肼
49 1-Methyl-2-pyrrolidone N-甲基吡咯烷酮
50 1,2,3-Trichloropropane 1,2,3-三氯丙烷
51 1,2-Benzenedicarboxylic acid,di-C6-8-branched alkyl esters,C7-rich(DIHP)
邻苯二甲酸二(C6-8支链)烷基酯,富C7(DIHP)
第六批20 种SVHC (2011 年12 月19日公布)
The sixth twenty Substances of Very High Concern (Released in Dec, 2011)
52 Dichromium tris(chromate)* 铬酸铬*
53 Potassium hydroxyoctaoxodizincatedichromate* 氢氧化铬酸锌钾*
54 Pentazinc chromate octahydroxide* 锌黄(C.I.颜料黄 36)*
55 Aluminosilicate Refractory Ceramic Fibres (RCF)* 硅酸铝耐火陶瓷纤维(RCF)*
56 Zirconia Aluminosilicate Refractory Ceramic Fibres(Zr-RCF)* 氧化锆硅酸铝耐火陶瓷纤维 (Zr-RCF)*
57 Formaldehyde, oligomeric reaction products with aniline (technical MDA)甲醛苯胺共聚物
58 Bis(2-methoxyethyl) phthalate (DMEP) 邻苯二甲酸二甲氧乙酯 (DMEP)
59 2-Methoxyaniline; o-Anisidine 邻甲氧基苯胺
60 4-(1,1,3,3-tetramethylbutyl)phenol,(4-tert-Octylphenol) 对特辛基苯酚
61 1,2-Dichloroethane 1,2-二氯乙烷
62 Bis(2-methoxyethyl) ether 二乙二醇二甲醚
63 Arsenic acid* 砷酸*
64 Calcium arsenate* 砷酸钙*
65 Trilead diarsenate* 砷酸铅*
66 N,N-dimethylacetamide (DMAC) N,N-二甲基乙酰胺(DMAC)
67 2,2'-dichloro-4,4'-methylenedianiline (MOCA) 2,2'-二氯-4,4'-二氨基二苯基甲烷(MOCA)
68 Phenolphthalein 酚酞
69 Lead diazide Lead azide * 叠氮化铅*
70 Lead styphnate* 2,4,6-三硝基苯二酚铅 (收敛酸铅)*
71 Lead dipicrate* 苦味酸铅*
第七批13 种SVHC (2012 年6 月18日公布)
The seventh thirteen Substances of Very High Concern (Released in June ,2012)
72 1,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme) 三甘醇二甲醚(TEGDME )
73 1,2-dimethoxyethane; ethylene glycol dimethyl ether(EGDME)1,2-二甲氧基乙烷 (EGDME)
74 Diboron trioxide* 三氧化二硼*
75 Formamide 甲酰胺
76 Lead(II) bis(methanesulfonate) * 甲基磺酸铅*
77 TGIC(1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione) 1,3,5-三缩水甘油-S-三嗪三酮;异氰 尿酸三缩水甘油酯(TGIC)
78 β-TGIC(1,3,5-tris[(2Sand2R)-2,3-epoxypropyl]-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione)
1,3,5-三(环氧乙烷基甲基)-1,3,5-三嗪-2,4,6-(1H,3H,5H)-三酮立体异构体
79 4,4'-bis(dimethylamino) benzophenone (Michler'sketone)4,4'-二(N,N-二甲氨基)二苯甲酮 90-94-8 202-027-5
80 N,N,N',N'-tetramethyl-4,4'-methylenedianiline(Michler's base)N,N,N'N'-四甲基-4,4'-二氨基二苯甲烷
81 C.I. Basic Violet 3 碱性紫3
82 C.I.Basic Blue 26 碱性蓝26
83 C.I. Solvent Blue 4 溶剂蓝4
84 4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcoholα,α -二[(二甲氨基)苯基]-4-甲氨基苯甲醇
第八批54 种SVHC (2012 年12 月17 日公布)
The eighth fifty-four Substances of public consulitation (end on 18 October 2012)
85 Bis(pentabromophenyl) ether (DecaBDE) 十溴联苯醚
85 Bis(pentabromophenyl) ether (DecaBDE) 十溴联苯醚
86 Pentacosafluorotridecanoic acid 全氟十三酸
87 Tricosafluorododecanoic acid 全氟十二酸
88 Henicosafluoroundecanoic acid 全氟十一烷酸
89 Heptacosafluorotetradecanoic acid 全氟十四酸
90 4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated 对特辛基苯酚
91 4-Nonylphenol, branched and linear 4-壬基苯酚,支链和直链
92 Diazene-1,2-dicarboxamide (C,C'-azodi(formamide))偶氮二甲酰胺
93 Cyclohexane-1,2-dicarboxylic anhydride (Hexahydrophthalic anhydride - HHPA) 六氢邻苯二甲酸酐
94 Hexahydromethylphathalic anhydride,
Hexahydro-4-methylphathalic anhydride,
Hexahydro-1-methylphathalic anhydride,
Hexahydro-3-methylphathalic anhydride
甲基六氢苯酐、4-甲基六氢苯酐、甲基六氢化邻苯二甲酸酐、3-甲基六氢苯二甲酯酐
95 Methoxy acetic acid甲氧基乙酸
96 1,2-Benzenedicarboxylic acid, dipentylester,branched and linear 支链和直链1,2-苯二羧二戊酯
97 Diisopentylphthalate (DIPP) 邻苯二甲酸二异戊酯
98 N-pentyl-isopentylphtalate 邻苯二甲酸正戊基异戊基酯
99 1,2-Diethoxyethane 乙二醇二乙醚
100 N,N-dimethylformamide; dimethyl formamideN,N-二甲基甲酰胺
101 Dibutyltin dichloride (DBT) 二丁基二氯化锡
102 Acetic acid, lead salt, basic 碱式乙酸铅
103 Basic lead carbonate (trilead bis(carbonate)dihydroxide)* 碱式碳酸铅*
104 Lead oxide sulfate (basic lead sulfate) 碱式硫酸铅
105 [Phthalato(2-)]dioxotrilead (dibasic lead phthalate)[1,2-苯二羧酸根合]二氧化三铅
106 Dioxobis(stearato)trilead 双(十八酸基)二氧代三铅
107 Fatty acids, C16-18, lead salts C16-18-脂肪酸铅盐
108 Lead bis(tetrafluoroborate)* 四氟硼酸铅*
109 Lead cynamidate* 氨基氰铅盐*
110 Lead dinitrate* 硝酸铅*
111 Lead oxide (lead monoxide) * 氧化铅*
112 Lead tetroxide (orange lead) * 四氧化三铅, 铅丹*
113 Lead titanium trioxide* 钛酸铅* 235-038-9
114 Lead Titanium Zirconium Oxide* 钛酸铅锆
115 Pentalead tetraoxide sulphate* 氧化铅与硫酸铅的复合物*
116 Pyrochlore, antimony lead yellow* 铅锑黄*
117 Silicic acid, barium salt, lead-doped* 铅掺杂的硅钡酸盐*
118 Silicic acid, lead salt 硅酸铅 234-363-3
119 Sulfurous acid, lead salt, dibasic* 亚硫酸铅(II)*
120 Tetraethyllead 四乙基铅
121 Tetralead trioxide sulphate* 三碱式硫酸铅*
122 Trilead dioxide phosphonate* 磷酸氧化铅*
123 Furan 呋喃
124 Propylene oxide; 1,2-epoxypropane; methyloxirane环氧丙烷
125 Diethyl sulphate 硫酸二乙酯
126 Dimethyl sulphate 硫酸二甲酯
127 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine3-乙基-2-甲基-2-(3-甲基丁基)-1,3-恶唑烷
128 Dinoseb 地乐酚(二硝丁酚)
129 4,4'-methylenedi-o-toluidine4,4'-二氨基-3,3'-二甲基二苯甲烷
130 4,4'-oxydianiline and its salts 4,4'-二氨基二苯醚
131 4-Aminoazobenzene; 4-Phenylazoaniline 4-氨基偶氮苯
132 4-methyl-m-phenylenediamine (2,4-toluene-diamine)2,4-二氨基甲苯
133 6-methoxy-m-toluidine (p-cresidine) 2-甲氧基-5-甲基苯胺
134 Biphenyl-4-ylamine 4-氨基联苯
135 o-aminoazotoluene 邻氨基偶氮甲苯
136 o-Toluidine; 2-Aminotoluene 邻甲基苯胺
137 N-methylacetamide N-甲基乙酰胺
138 1-bromopropane; n-propyl bromide 溴代正丙烷
备注:*代表无机化合物